Pour the water into a mixing bowl and add the gelatin. Attach the bowl to the stand mixer and fit the whisk attachment.
In a heavy-bottomed pot, boil the sugar, agave, and water over medium heat for 10-13 minutes, until the mixture reaches between 240-250 F.
With the mixer running on low, slowly stream the hot sugar into the mixing bowl with the gelatin. Aim the stream so it goes between the whisk and the side of the bowl. If you pour it onto the whisk you'll end up with hard bits of sugar in your marshmallows. Once it has been added, add the vanilla bean paste and salt. Increase the speed to medium and mix for 10-15 minutes, or until the bowl no longer feels hot. It should feel warm and the marshmallow should be thick and fluffy.
Working quickly, scrape the marshmallow directly on top of the brownie. Use the spatula to evenly spread it to fill the pan. Set the brownies aside to set for a minimum of 4 hours.
When you are ready to cut them, pull the sides of the parchment up to remove them from the pan and place it on a cutting board. Have a small bowl of canola oil or nonstick cooking spray nearby with a few paper towels and a sharp knife.
Dust the top of the marshmallow with a thin layer of powdered sugar.
Run the knife under hot water, then wipe it clean. Dab a paper towel in the oil and rub it all over the blade of the knife.
Cut the brownie into four sections from the middle to one edge in one clean cut. Then run the knife under hot water, grease it, and cut the brownie from the opposite side in the same way. You can watch the step-by-step video below for a visual example. Separate the sections, then cut each one into fourths. Continue with these same steps until the entire pan of s'mores brownies are cut.
Place the individual brownies on a sheet pan. Use a kitchen torch or put them under the oven broiler until the tops are golden brown. Enjoy!